Abstract
There is nearly unanimous consensus amongst scientists that increasing greenhouse gas emissions, including CO2 generated by human activity, are affecting the Earth‘s climate. Climate change has the potential to overwhelm existing capacities, as well as durability of concrete infrastructure. Carbonation of concrete occurs due to a reaction between atmospheric CO2 and the hydrated phases of concrete, leading to a drop in its pH and the depassivation of embedded rebar. Therefore, increases in carbonation rates of reinforced concrete structures are expected as a result of increased temperatures and CO2 concentrations, with the enhanced risk of carbonation induced corrosion likely affecting the longevity of our concrete infrastructure. This thesis considered the potential consequences of global climate change on our concrete infrastructure, with the objective being to determine if there is an increased risk of deterioration due to carbonation induced corrosion. A unique numerical model was developed to determine carbonation rates in structures, and verified through experimental tests. The model was applied to a numbers of cities in locations throughout the world to determine where structures were most vulnerable. Additionally, a number of other laboratory experiments were carried out to supplement the numerical model and provide insights as to how carbonation progress can be monitored within a structure. Using the model developed, and inputting forecasts for increases in future atmospheric CO2 concentrations and weather conditions, it was shown that for medium quality, non-pozzolonic concrete in geographic areas where carbonation induced corrosion is a concern, global climate change will affect its progress in our concrete infrastructure. We will see much higher ultimate carbonation depths in the long term. The use of non-destructive testing (NDT) methods, and structural health monitoring (SHM) techniques could be invaluable in monitoring the progress of carbonation in a structure, but the data generated by the methods and techniques used must be analyzed carefully before making any conclusions. For the NDT methods and carbonation pH sensors which were evaluated in this study, it was found that ambient test conditions had a major impact on results.,Thesis,Published.